Not sure if anyone has stated this before but I fixed my errors that were occuring in HL2. I am using the 5.7 Cats, I turned off Vsync, I disabled VPU, and disabled Catalyst A.I. I think the main problem was with the VPU and A.I. Vsync should be fine. HL2 now loads up fine and never locks up at all. I can even alt-tab out with ease.
Oh and when VPU is off be sure to have no type of overclocking on, not even the ATI overdrive should be on.
Oh and when VPU is off be sure to have no type of overclocking on, not even the ATI overdrive should be on.