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Hmm I can recommend quite a few mods, but I have no clue about modding the steam version. I've read a few times that the steam version isn't modded as willingly as the retail version. Anyway, my recommendation list would be as follows.
graphics
S.W.O. (2.2.2 is the newest) (includes SHARPER, stalker skies and an optional Sky4ce shader mod (which you should not install)
Float32
Fallout flashlight
gameplay
Endurance
Non degrading armor and weapons
No timelimit on quests
Then you should add into the launchoptions "-smap4096 -nointro".
I personally also did my own weapon mod that tripples all damage from any gun. It makes the game quite more interesting (but HARD). I can send you that, and include my own customized user.ltx and weather_default.ltx if you're interested.
My results can be seen here. http://www.halflife2.net/forums/showthread.php?p=2709299#post2709299
srsly what mods should I use with my steam version.