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Get GIMP, it's free (and equal to Photoshop).
I think he should learn how to use Photoshop, before start using Painter.
Don't buy Corel, it is in fact a cancer. I have so many issues with that program.
If you want to make decent Digital Art, Painter is a better choice by far. There really isn't anything that Photoshop does on the artistic side that Painter doesn't do better. Ideally it's nice to have both, but you could just as easily have PSP & Painter X both for less than the cost of one licence of PS CS4 and manage perfectly well. Unless you're a photographic professional buying a PS CS4 licence is kind of a waste of money imho. where I work we use it, but the depth of the application is hardly ever used. It's like having a SUV to drive to the corner shop.
Photoshop is something necessary to cleanup images, draw lines and so on. I can't imagine using Painter without it.
I've tried to get the hang of Painter so many times but I just can't some people can do amazing things with it but I can't get over the interface. All I get out of it is immense frustration