Potemkin
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"(the infamous Schmidt Sting Pain Index excludes insects other than Hymenoptera; a belostomatid bite can be much more excruciating than anything in Schmidt's list)"I thought bullet ant has the most painful sting/bite?
"Hymenoptera is one of the larger orders of insects, comprising the sawflies, wasps, bees, and ants."
That means that the index only deals with sawflies, wasps, bees and ants. All other insects are left out in the proverbial cold.
I'm not saying that the bite of a giant water bug is the last word as far as pain is concerned, just because Wiki says so, but then again, I have no real reason for not believing it, y'know?